I was reading the description of both GotOrderEMailTo and MailMe_ToAddress and have found that they have the same description:
GotOrderEMailTo: Who gets notified of new orders. This is typicall the e-mail address that the store administrator monitors.
MailMe_ToAddress: The e-mail address you want order notifications to be sent to, usually the same as MailMe_FromAddress, e.g. sales@yourdomain.com
So which one is actually for new orders? And what is the other one for?